Photochromism of photopolymerized novel copolymers having spirooxazine moiety groups

Iranian Polymer Journal - A novel class of photochromic copolymer based on spironaphthoxazine (SO) moieties was smoothly prepared through the copolymerization of methyl methacrylate (MMA), butyl...     

SiO2疏松体高温脱羟过程数值模拟(续)

3.2脱羟过程主要参数变化图5所示为熔制过程中SiO2疏松体平均温度(Ta)和平均孔隙率(φa)随时间的变化曲线。可以看出,疏松体平均温度的升高趋势和图3所示的顶面升温曲线保持一致。在10h时顶面温度为1 000℃,疏松体平均温度为997.5℃,两者较为接近。这是由于高温下辐射换热较为强烈,顶面的高温很快传递到疏松体内部。由于35h之前疏松体还未烧结,所以φa保持初始值不变。在35h以后,疏松体开始发生烧结,φa开始下降。当脱羟进行到76.3h时,疏松体全部烧结为石英锭,此后随着温度升高石英锭的孔隙率维持在设定的最低值0.01。     

Effect of clad ratio on interfacial microstructure and properties of cladding billets via direct-chill casting process

Numerical simulation and experiments were introduced to develop AA4045/AA3003 cladding billets with different clad-ratios. The temperature fields, microstructures and mechanical properties near interface were investigated in detail. The results show that cladding billets with different clad-ratios were fabricated successfully. Si and Mn elements diffused across the bonding interface and formed diffusion layer. With the increase of clad-layer thickness, the interfacial region transforms from semisolid–solid state to liquid–solid state and the diffusion layer increased from 10 to 25 μm. The hardness at interface is higher than that of AA3003 side but lower than that of the other side. The bonding strength increased with the clad-layer thickness, attributing to solution strengthening due to elements diffusion. The cladding billets were extruded into clad pipe by indirect extrusion process after homogenization. The clad pipe remained the interfacial characteristics of as-cast cladding billet and the heredity of clad-ratio during deformation was testified.     

基于Faster R-CNN的颜色导向火焰检测

基于深度特征的目标检测方法Faster R-CNN在火焰检测任务上存在检测效率低的问题,因此提出了基于颜色引导的抛锚策略。该策略设计火焰颜色模型来限制锚的生成,即利用火焰颜色约束锚的生成区域,从而减少了初始锚的数量,提升了计算效率。为了进一步提高网络的计算效率,将区域生成网络中的卷积层替换成掩膜卷积。为了验证所提方法的检测效果,采用BoWFire和Corsician数据集进行验证。实验结果表明,该方法实际检测速度相较于原Faster R-CNN提高了10.1%,BoWFire上该方法的火焰检测F值为0.87,Corsician上该方法的准确度可达99.33%。所提方法可以提高火焰检测的效率,并能够准确检测图像中的火焰。     

Beta-Binomial删除信道中的喷泉码文件传输协议

由于命名数据网络(NDN,Named-Data Networking)无环路、逐包、逐跳转发的特点,使得数据包回传成功率降低,而传统的TCP/IP协议中的ARQ和ACK机制对于多播会话不再适用.由于NDN中的传输信道可以等效为二进制删除信道,因此可以通过应用层编码来实现文件的可靠传输.传统的信道编码技术如卷积码、级联码和RS码等复杂度较高,而将NDN与低复杂度的喷泉码的结合可以实现分布式的存储架构,因而可通过喷泉编码在应用层协议中实现可靠的纠删机制,保证整体文件的传输可靠性.以往的研究一般是基于确定的删除概率信道模型,但是由于网络的异构性和信道噪声等因素影响,可能会造成信道丢包概率呈随机性分布.因此,本文在Beta-Binomial分布模型的前提下,根据贝叶斯统计的先验信息和中心极限定理,对随机概率下的纠删信道的文件可靠传输协议进行了数学建模和理论推导.仿真结果显示此模型更具有普适性,此传输协议可在信道状况未知的前提下从理论上求出最小发包数,减少冗余编码包,提高文件整体的投递成功率,在保证传输可靠性的同时有效提升协议传输效率.     

基于RG 1.183的先进小堆选址源项模型初步研究

在《用于评估核动力反应堆设计基准事故的替代放射性源项》RG 1.183所述的假想事故场景情况下,考虑目前大多数的先进小型压水堆地上-地下布置的设计特点,对传统大型压水堆选址源项计算模型做了改进:在原安全壳内放射性物质守恒方程的基础上,考虑辅助厂房的阻滞作用,建立辅助厂房内放射性物质守恒方程。并以某先进小型反应堆核电厂为例,利用新模型计算了代表核素的释放,与现有模型进行了对比。     

原油及馏分油脱酸技术进展

石油酸是原油和馏分油中普遍存在的腐蚀性物质，其主要成分为环烷酸并且含量可以高达90%以上。环烷酸具有羧酸的所有化学性质，所以常常造成严重的腐蚀，从而影响原油加工设备及油品使用设备的正常运行和使用寿命。随着近年来世界范围内高酸原油产量的逐渐增加，高原油及各种高酸值馏分油所带来的腐蚀与产品质量问题显得愈发严重，因此迫切需要开发出经济高效的脱酸技术与工艺路线。本文较为全面而详细地总结并评述了国内外原油及油品的各种脱酸技术方法。分析表明：目前所报道的各类脱酸工艺较多，其中工业应用的加氢脱酸效果虽好但是成本较高，而其他大多数脱酸方法都存在较多的缺点或不足，因此探寻一种绿色环保、经济高效并且具有较好普适性的油品脱酸工艺显得非常迫切而必要。酯化法脱酸具有加工工艺简单、不需要复杂的后继处理，几乎可以降低所有的高酸值原油和油品（轻质、重质馏分油以及渣油）的酸值，为原料油的进一步加工提供了方便。酯化脱酸工艺的关键在于高效催化剂的选择，而目前的催化酯化体系虽然脱酸率较高，但仍存在着反应时间较长的不足，相信通过反应过程强化等手段解决该问题以后，催化酯化脱酸工艺会被很快投入到原油及油品的脱酸实际工业生产中去。     

Efficient atom localization via probe absorption in an inverted-Y atomic system

The behaviour of atom localization in an inverted-Y atomic system is theoretically investigated. For the atoms interacting with a weak probe field and several orthogonal standing-wave fields, their position information can be obtained by measuring the probe absorption. Compared with the traditional scheme, we couple the probe field to the transition between the middle and top levels. It is found that the probe absorption sensitively depends on the detuning and strength of the relevant light fields. Remarkably, the atom can be localized at a particular position in the standing-wave fields by coupling a microwave field to the transition between the two ground levels.     

Solvent-Free Plasticity and Programmable Mechanical Behaviors of Engineered Proteins

Biopolymeric networks with plasticity show great competences in diverse fields owing to the combined biocompatible and mechanical characteristics. However, to realize such plasticity external complicated treatments, e.g., UV or organic solvent have to be applied, which in turn impair the biological nature and even mechanical properties of those systems. To address this challenge, one new type of anhydrous protein liquid crystalline (LC) gels, which exhibit flexible morphological plasticity and mechanical programmability is demonstrated. Supramolecular interactions in the smectic biogels play an important role for their high plasticity. Remarkably, the samples exhibit outstanding mechanical behaviors. The tensile strength and Young's modulus at MPa levels are comparable or even higher than chemically cross-linked hydrogels and LC elastomers. More importantly, mechanical programmability of the LC gels is achieved by genetically tuning the charge density of protein backbones. Consequently, the mechanical performance is manipulated in the range of one order of magnitude. Thus, this type of anhydrous protein LC gels offers great opportunities for load-bearing high-tech applications.